The Great London:
Space Exploration

Scientists have discovered that the mineral jarosite breaks down organic compounds when it is flash-heated, with implications for Mars research.

Jarosite is an iron sulphate and it is one of several minerals that NASA’s Curiosity Mission is searching for, as its presence could indicate ancient habitable environments, which may have once hosted life on the red planet.

In a new study published today in the journal Astrobiology, researchers from Imperial College London and the Natural History Museum replicated a technique that one of the Curiosity Rover’s on-board instruments is using to analyse soil samples, in its quest to find organic compounds. They tested a combination of jarosite and organic compounds. They discovered that the instrument’s technique -which uses intense bursts of heat called flash-heating – broke down jarosite into sulphur dioxide and oxygen, with the oxygen then destroying the organic compounds, leaving no trace of it behind.

The concern is that if jarosite is present in soil samples that Curiosity analyses, researchers may not be able to detect it because both the jarosite and any organic compounds could be destroyed by the flash-heating process.

In 2014, Professor Mark Sephton, co-author of today’s study, investigated the mineral perchlorate. This mineral also causes problems for flash-heating experiments as it breaks down to give off oxygen and chlorine gas, which in turn react with any organic compounds, breaking them down into carbon dioxide and water. Professor Sephton showed that though perchlorate was problematic, scientists could potentially use the carbon dioxide resulting from the experiment to detect the presence of organic compounds in the sample being analysed.

Professor Sephton, from the Department of Earth Science and Engineering at Imperial College London, said: “The destructive properties of some iron sulphates and perchlorate to organic matter may explain why current and previous missions have so far offered no conclusive evidence of organic matter preserved on Mars’ surface. This is despite the fact that scientists have known from previous studies that organic compounds have been delivered to Mars via comets, meteorites and interplanetary dust throughout its history.”

To make Curiosity’s search for signs of life more effective, the team are now exploring how Curiosity might be able to compensate for the impact of these minerals on the search for organic compounds. Their work could have important implications for both the Curiosity mission and also the upcoming European-led ExoMars 2018 Rover mission, which will be drilling for subsurface samples of the red planet and using the same flash-heating method to look for evidence of past or present alien life.

James Lewis, co-author of the study from the Department of Earth Science and Engineering at Imperial College London, added: “Our study is helping us to see that if jarosite is detected then it is clear that flash-heating experiments looking for organic compounds may not be completely successful. However, the problem is that jarosite is evidence of systems that might have supported life, so it is not a mineral that scientists can completely avoid in their analysis of soils on Mars. We hope our study will help scientists with interpreting Mars data and assist them to sift through the huge amount of excellent data that Curiosity is currently generating to find signs that Mars was once able to sustain life.”

On Earth, iron sulphate minerals like jarosite form in the harsh acidic waters flowing out of sulphur rich rocks. Despite the adverse conditions, these waters are a habitat for bacteria that use these dissolved sulphate ions. This makes these minerals of great interest to scientists studying Mars, as their presence on the red planet provide evidence that acidic liquid water was present at the same time the minerals formed, which could have provided an environment favourable for harbouring ancient microbial Martian life.

On board Curiosity, the Sample Analysis at Mars (SAM) instrument analyses soil samples for evidence of organic compounds by progressively heating samples up to around 1000 C, which releases gases. These gases can then be analysed by techniques called gas chromatography and mass spectrometry, which can identify molecules in the gas and see if any organic compounds are present. It is these SAM instrument experiments that the researchers behind today’s study replicated with jarosite and organic compounds.

The researchers stress that not all sulphates break down to react with organic compounds. For example, those containing calcium and magnesium would not break down until extremely high temperatures were reached during the analysis, and therefore would not affect any organic compounds present.

The team suggest that if jarosite is found in samples on Mars, then it may be possible for Curiosity’s SAM instrument to distinguish a spike in carbon dioxide level, which, as Professor Sephton has shown previously with perchlorate, would act as an indicator that organic material is present and being broken down by the heating process.

The next step will see the researchers using synthetic jarosite in their experiments, which will enable a cleaner decomposition process to occur when the mineral is flash-heated. This will allow for more precise quantitative measurements to be taken when the oxygen is being released. Ultimately, they hope this will enable more precise calculations to be carried out on Mars mineral samples to find ways in which Curiosity can identify the presence of these mineral to mitigate their impact on organic matter.

The jarosite samples used in the experiments in the study were collected from Brownsea Island in Dorset, with the permission and assistance from the National Trust.

Source: Imperial College London [February 19, 2015]

Some of the final results sent back by ESA's Venus Express before it plummeted down through the planet's atmosphere have revealed it to be rippling with atmospheric waves – and, at an average temperature of -157°C, colder than anywhere on Earth.

As well as telling us much about Venus' previously-unexplored polar regions and improving our knowledge of our planetary neighbour, the experiment holds great promise for ESA's ExoMars mission, which is currently winging its way to the Red Planet. The findings were published in the journal Nature Physics.

ESA's Venus Express arrived at Venus in 2006. It spent eight years exploring the planet from orbit, vastly outliving the mission's planned duration of 500 days, before running out of fuel. The probe then began its descent, dipping further and further into Venus' atmosphere, before the mission lost contact with Earth (November 2014) and officially ended (December 2014).

However, Venus Express was industrious to the end; low altitude orbits were carried out during the final months of the mission, taking the spacecraft deep enough to experience measurable drag from the atmosphere. Using its onboard accelerometers, the spacecraft measured the deceleration it experienced as it pushed through the planet's upper atmosphere – something known as aerobraking.

"Aerobraking uses atmospheric drag to slow down a spacecraft, so we were able to use the accelerometer measurements to explore the density of Venus' atmosphere," said Ingo Müller-Wodarg of Imperial College London, UK, lead author of the study. "None of Venus Express' instruments were actually designed to make such in-situ atmosphere observations. We only realised in 2006 – after launch! – that we could use the Venus Express spacecraft as a whole to do more science."

When Müller-Wodarg and colleagues gathered their observations Venus Express was orbiting at an altitude of between 130 and 140 kilometres near Venus' polar regions, in a portion of Venus' atmosphere that had never before been studied in situ.

Previously, our understanding of Venus' polar atmosphere was based on observations gathered by NASA's Pioneer Venus probe in the late 1970s. These were of other parts of Venus' atmosphere, near the equator, but extrapolated to the poles to form a complete atmospheric reference model.

These new measurements, taken as part of the Venus Express Atmospheric Drag Experiment (VExADE) from 24 June to 11 July 2014, have now directly tested this model – and reveal several surprises.

For one, the polar atmosphere is up to 70 degrees colder than expected, with an average temperature of -157°C (114 K). Recent temperature measurements by Venus Express' SPICAV instrument (SPectroscopy for the Investigation of the Characteristics of the Atmosphere of Venus) are in agreement with this finding.

The polar atmosphere is also not as dense as expected; at 130 and 140 km in altitude, it is 22% and 40% less dense than predicted, respectively. When extrapolated upward in the atmosphere, these differences are consistent with those measured previously by VExADE at 180 km, where densities were found to be lower by almost a factor of two.

"This is in-line with our temperature findings, and shows that the existing model paints an overly simplistic picture of Venus' upper atmosphere," added Müller-Wodarg. "These lower densities could be at least partly due to Venus' polar vortices, which are strong wind systems sitting near the planet's poles. Atmospheric winds may be making the density structure both more complicated and more interesting!"

Additionally, the polar region was found to be dominated by strong atmospheric waves, a phenomenon thought to be key in shaping planetary atmospheres – including our own.

"By studying how the atmospheric densities changed and were perturbed over time, we found two different types of wave: Atmospheric gravity waves and planetary waves," explained co-author Sean Bruinsma of the Centre National D'Etudes Spatiales (CNES), France. "These waves are tricky to study, as you need to be within the atmosphere of the planet itself to measure them properly. Observations from afar can only tell us so much."

Atmospheric gravity waves are similar to waves we see in the ocean, or when throwing stones in a pond, only they travel vertically rather than horizontally. They are essentially a ripple in the density of a planetary atmosphere – they travel from lower to higher altitudes and, as density decreases with altitude, become stronger as they rise. The second type, planetary waves, are associated with a planet's spin as it turns on its axis; these are larger-scale waves with periods of several days.

We experience both types on Earth. Atmospheric gravity waves interfere with weather and cause turbulence, while planetary waves can affect entire weather and pressure systems. Both are known to transfer energy and momentum from one region to another, and so are likely to be hugely influential in shaping the characteristics of a planetary atmosphere.

"We found atmospheric gravity waves to be dominant in Venus' polar atmosphere," added Bruinsma. "Venus Express experienced them as a kind of turbulence, a bit like the vibrations you feel when an aeroplane flies through a rough patch. If we flew through Venus' atmosphere at those heights we wouldn't feel them because the atmosphere just isn't dense enough, but Venus Express' instruments were sensitive enough to detect them."

Venus Express found atmospheric waves at an altitude of 130-140 km that the team think originated from the upper cloud layer in Venus' atmosphere, which sits at and below altitudes of approximately 90 km, and a planetary wave that oscillated with a period of five days. "We checked carefully to ensure that the waves weren't an artefact of our processing," said co-author Jean-Charles Marty, also of CNES.

This is not just a first for Venus Express; while the aerobraking technique has been used for Earth satellites, and was previously used on NASA-led missions to Mars and Venus, it had never before been used on any ESA planetary mission.

However, ESA's ExoMars Trace Gas Orbiter, which launched earlier this year, will use a similar technique. "During this activity we will extract similar data about Mars' atmosphere as we did at Venus," added Håkan Svedhem, project scientist for ESA's ExoMars 2016 and Venus Express missions.

"For Mars, the aerobraking phase would last longer than on Venus, for about a year, so we'd get a full dataset of Mars' atmospheric densities and how they vary with season and distance from the Sun," added Svedhem. "This information isn't just relevant to scientists; it's crucial for engineering purposes as well. The Venus study was a highly successful test of a technique that could now be applied to Mars on a larger scale – and to future missions after that."

Source: European Space Agency [April 19, 2016]

The surface of Mars – including the location of Beagle-2 – has been shown in unprecedented detail by UCL scientists using a revolutionary image stacking and matching technique.

Exciting pictures of the Beagle-2 lander, the ancient lakebeds discovered by NASA's Curiosity rover, NASA's MER-A rover tracks and Home Plate's rocks have been released by the UCL researchers who stacked and matched images taken from orbit, to reveal objects at a resolution up to five times greater than previously achieved.

A paper describing the technique, called Super-Resolution Restoration (SRR), was published in Planetary and Space Science in February but has only recently been used to focus on specific objects on Mars. The technique could be used to search for other artefacts from past failed landings as well as identify safe landing locations for future rover missions. It will also allow scientists to explore vastly more terrain than is possible with a single rover.

Co-author Professor Jan-Peter Muller from the UCL Mullard Space Science Laboratory, said: "We now have the equivalent of drone-eye vision anywhere on the surface of Mars where there are enough clear repeat pictures. It allows us to see objects in much sharper focus from orbit than ever before and the picture quality is comparable to that obtained from landers.

"As more pictures are collected, we will see increasing evidence of the kind we have only seen from the three successful rover missions to date. This will be a game-changer and the start of a new era in planetary exploration."

Even with the largest telescopes that can be launched into orbit, the level of detail that can be seen on the surface of planets is limited. This is due to constraints on mass, mainly telescope optics, the communication bandwidth needed to deliver higher resolution images to Earth and the interference from planetary atmospheres. For cameras orbiting Earth and Mars, the resolution limit today is around 25cm (or about 10 inches).

By stacking and matching pictures of the same area taken from different angles, Super-Resolution Restoration (SRR) allows objects as small as 5cm (about 2 inches) to be seen from the same 25cm telescope. For Mars, where the surface usually takes decades to millions of years to change, these images can be captured over a period of ten years and still achieve a high resolution. For Earth, the atmosphere is much more turbulent so images for each stack have to be obtained in a matter of seconds.

The UCL team applied SRR to stacks of between four and eight 25cm images of the Martian surface taken using the NASA HiRISE camera to achieve the 5cm target resolution. These included some of the latest HiRISE images of the Beagle-2 landing area that were kindly provided by Professor John Bridges from the University of Leicester.

"Using novel machine vision methods, information from lower resolution images can be extracted to estimate the best possible true scene. This technique has huge potential to improve our knowledge of a planet's surface from multiple remotely sensed images. In the future, we will be able to recreate rover-scale images anywhere on the surface of Mars and other planets from repeat image stacks" said Mr Yu Tao, Research Associate at UCL and lead author of the paper.

The team's 'super-resolution' zoomed-in image of the Beagle-2 location proposed by Professor Mark Sims and colleagues at the University of Leicester provides strong supporting evidence that this is the site of the lander. The scientists plan on exploring other areas of Mars using the technique to see what else they find.

View the image gallery on Flickr.

Source: University College London [April 26, 2016]